4064 will work get with a variety of bullets including the 100g but it is on the slower side.
If you want speed with accuracy with the 80-85g, then R#19 with the win primer will get you all over 3200-3300 fps. Plan on bumping the shoulder or full length sizing after ever firing where the accuracy node is. R#19 produces a very accurate hunting load with SPEED. However, the load is on the warm side...I use it hunting.
Also, IMR4064 with the 80g Sierra and 80g Tipped triple shock, if you work up till you see pressure you will find really great accuracy at 3400 fps area.
I use the Forster/Bonanza neck dies and bump the shoulders back .002 on every firing and will get away from FL sizing when I will trim the cases which is usually around 4-5 firings.
In my coyote loads in many 700's, usually the 70g will love a 39g IMR 4064 load with a Fed 210, and the 80g will be either 41.5-42.0, and work up to that load in your rifle as it is warm. R#19 in my 24" rem 700 will be 3250 +/- a tad, and if you get a good lot of 87V's you are in the money. For example, I shoot a load of 44.5g of R#19 with the 85g Barnes tipped triple shock with a .050 jump and get less than 1/2" group accuracy out of 700's that have been bedded and free floated.
So, I will use 4064 till the 80g, then switch to the R#19 for 85-87g bullets. Then H or IMR 4350 for the 95-100g bullets out of habit. I am sure that R#19 would shine with the 100g, but supplies have been tight for years now, have to use what you can find.