Originally Posted By: CatShooterOriginally Posted By: Raymond Blaker
Nitro powder doesn't ignite all at ones, but burns at controlled rates depending on the powder type. Black powder ignites all at once and is hence a class one explosive, whereas nitro powder is a class 6 explosive.
Check your powder burn rates, another example, take sugar, flour, or even metal shavings and chuck it balled into a fire, it will burn but slowly, now throw it into the fire as a dust, and it will explode, same thing will happen of you have a reduced powder load where the primer goes over the lot in one go.
This keeps getting dumber and dumber. Do you know what the burn rates are - I think not, based on your examples.
Black powder does not burn all at once - the burning rate for black powder is 96 inches per second - which means if you have a solid stick of black powder that is 96 feet long, it will take one second to burn if you light it at one end.
If you have a round ball of black powder that is 2 times 96 inches in diameter, and light it on all sides at one, it will take one second to burn.
If you have a grain of black powder that is 1/1,000 that size (0.096") it will burn in 1/1,000th of a second. One forth that size (0.024") will burn in 1/4,000 of a second.. and so on.
It makes no difference what the pressure is, black powder burns at a constant speed.
The black powder burns ON the surface of the grain - the "flame" is actually part of the surface, which is why the burning speed is constant.
Smokeless powder does NOT burn at a fixed speed, and technically, it does not burn at all - it "Deflagerates".
It goes through a two stage decomposition process. The grains are heated and put under pressure by the primer. The grain surface first melts, and then breaks down to several very large, complex molecule, gases which are given off from the melted surface - it is these gases that create the flame as they devolve into new, simpler gases that take up more space and generate more heat because of the broken carbon bonds.
In the open air, a pile of 4895 can take 5 or more seconds to burn. There is no "flash-over". You light the pile at one end, and it burns slowly across the pile.
Smokeless powder is totally dependent of the pressure it is burning in - the higher the pressure, the faster it burns... which (for those that live in Rio Linda), is why it is called "progressive" burning powder. The "Speed" rating of smokeless powder are done under high pressure, and are relative to each other, not specific like black powder.
In a cartridge case, the primer heats the whole interior of the case and puts the powder under fairly high pressure. The powder grains light at the same time - the burning is NOT from one end to the other. Then the nitrocellulose starts it's two stage burning process.
As the pressure builds, the flame front gets pushed closer to the surface of the grain - the closer it gets, the hotter the surface of the grain gets, so the more gas is given off, which makes the pressures higher, which pushes the flame front closer to the surface of the grain - the closer it gets, the hotter the surface of the grain gets, so more gas is given off, which makes the pressures higher, which... on and on.
If the pressure drops before the grains are finished burning (the bullet leaves the barrel), the flame moves away from the surface of the grain, so the heat drops, so the grain gives off less gas, which causes the flame to move further away from the grain, and the whole thing is reversed - until the "fire" goes out and the remaining piece of the grain is left in the case, or barrel, or on the ground - unburned.
And THAT is why you will find unburned powder in barrels or cases.
I once witnessed a 45-70 being fired with a full case of 3031, and a 200gr lead pistol bullet - there was practicably no resistance for the bullet and it slipped out of the barrel like a piece of owl poop.
When the case was removed, a "solid" thing fell out of the case that looked like a cigar ash - it was a solid lump of 3031, where all the grains started to burn from the primer, and the grain surface started to melt, but there was not enough pressure to keep the flame going and it simply "went out", and all the grains fused together when it cooled.
I offered the guy $10 for the fused lump of powder, but he decided to light it with a match instead.
Back in 1978, I bought an interesting book.
The authors took the 243 and the 6mm Rem, and loaded EVERY powder available, from the fastest pistol, to the slowest machine gun powder, and used a strain gauge (very new at the time) to measure the pressures and plot the pressure curves. It was way before it's time, and I think even now, it is still before it's time.
But, with the prior comments about "flash over" and pressure problems with large space in a case, I thought these curves might throw some light (and truth) on the subject.
If you look carefully at the curves, you can see that they are predictable.
So - it should be obvious that "flash over" is impossible, and all these analogies about sawdust and other stuff, is pure garbage and fabrications.
As far as throwing dust in an open fire?? Do you really want us to take you seriously??
Please give us a break from silliness!!
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OK, so I have an applied fluid mechanics project to finish and final to prepare for, so I thought I would take a break and relax my brain a little on Predator Master's and I ran into Catshooter spanking somebody with facts that made my brain hurt more. I'm going back to Manning's equation, critical flow and hydraulic jump, at least I understand that.